|
|
geranylgeranyl_diphosphate <=> ent-copalyl_diphosphate
|
5.5.1.12
copalyl diphosphate synthase
5.5.1.13
ent-copalyl diphosphate synthase
5.5.1.14
syn-copalyl-diphosphate synthase
|
–
–
–
|
|
BRENDA:
BR40507;
BR44349;
BS386478
KEGG:
R02068;
R06298;
R06312
MetaCyc:
5.5.1.13-RXN;
RXN-4861;
RXN-8528
|
|
|
|
abieta-8,11,13-triene + reduced_[NADPH-hemoprotein_reductase] + O2 <=> ferruginol + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.175
ferruginol synthase
|
–
|
|
MetaCyc:
RXN-16786
|
|
|
|
11-hydroxyferruginol + reduced_[NADPH-hemoprotein_reductase] + O2 <=> carnosic_acid + oxidized_[NADPH-hemoprotein_reductase] + H2O + H+
|
1.14.14.61
carnosic acid synthase
|
–
|
|
MetaCyc:
RXN-18881
|
|
|
|
copalyl_diphosphate <=> miltiradiene + diphosphate
|
4.2.3.131
miltiradiene synthase
|
–
|
|
BRENDA:
BR50206
KEGG:
R10585
MetaCyc:
RXN-13338
|
|
|
|
miltiradiene + acceptor <=> abieta-8,11,13-triene + reduced_acceptor
|
not assigned
|
–
|
|
MetaCyc:
RXN-16785
|
|
|
|
ferruginol + reduced_[NADPH-hemoprotein_reductase] + O2 <=> 11-hydroxyferruginol + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.60
ferruginol monooxygenase
|
–
|
|
MetaCyc:
RXN-18880
|
|